CAS 112-34-5, chemical formula HOCH₂CH₂OCH₂CH₂O(CH₂)₃CH₃. Viscosity of the mixture (1) water; (2) diethylene glycol diethyl ether Wohlfarth, Ch. DIETHYLENE GLYCOL is incompatible with strong oxidizing agents. high boiling point, and low viscosity. Abstract. Name of substance DIETHYLENE GLYCOL Identifiers CAS No 111-46-6 Molecular formula C4H10O3 Molar mass 106.1 g/mol SECTION 4: First-aid measures 4.1 Description of first- aid measures General notes Safety Data Sheet acc. Diethylene glycol is used in the manufacture of unsaturated polyester resins, polyurethanes and plasticizers. 1,4-Dioxane - Wikipedia From the experimental data, the excess molar volume V E, viscosity … DOI: 10.1021/je025610o. It is widely used in the manufacture of unsaturated polyester resins, polyurethanes, nitrocellulose, resins and plasticizers. Heat is also generated by the … It is a water-soluble liquid; boiling point 245 C; soluble in many organic solvents. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 04/23/2018 Revision date: 04/23/2018 Supersedes: 10/20/2015 Version: 1.2 The density, viscosity, and thermal conductivity of ethylene glycol + water, diethylene glycol + water, and triethylene glycol + water mixtures were measured at temperatures ranging from 290 K to 450 K and concentrations ranging from 25 mol % glycol to 100 mol % glycol. Molar Mass The molar mass of ethylene glycol is 62 g/mol. Trova Produttore Diethylene Glicole Viscosità alta Qualità Diethylene Glicole Viscosità, Fornitori e Diethylene Glicole Viscosità prodotti al Miglior Prezzo su Alibaba.com Opinion on diethylene glycol 5 1. It is a hygroscopic liquid. Its molecular formula is C4H10O3 and has boiling point in 473oF at 760 mmHg and Melting point in 14oF. Maternal toxicity was evident in dams exposed to diethylene glycol diethyl ether at doses greater than or equal to 1,500 mg/kg/day . DIETHYLENE GLYCOL ETHYL ETHER ACETATE is an ester. However, under high vapor concentrations, a slightly sweet odor may be detected. For adjusting the viscosity, however, an addition of chain length modifier like ethylene glycol or diethylene glycol can also be used. U.S. Federal Regulations TSCA 12(b) Not applicable SARA 313 Not applicable SARA 311/312 Hazard CategoriesSee section 2 for more information CWA (Clean Water Act) Not applicable Clean Air Act Not applicable OSHA Occupational Safety and Health Administration Density, Viscosity, and Thermal Conductivity of Aqueous Ethylene, Diethylene, and Triethylene Glycol Mixtures between 290 K and 450 K. Journal of Chemical & Engineering Data 2003, 48 (1) , 198-202. Diethylene Glycol Safety Data Sheet according to Federal Register / Vol. Under normal conditions, diethylene glycol has no detectable odor; however, under high vapor concentrations, a slightly sweet odor may be detected. Diethylene glycol is used as an important industrial solvent due to its characteristic properties like high boiling point, high viscosity and low vapor loss. Diethylene glycol monobutyl ether for synthesis. Diethylene glycol dibutyl ether as inert, aprotic, high boiling sol-vent has wide applicability in various types of cleaning formula-tions. Diethylene Glycol (DEG) is a colorless, low-volatility, low viscosity, hygroscopic liquid. Propionic – offering reduced viscosity and improved solvent diffusion, propionic esters provide substantial flexibility in formulating automotive refinish, OEM, electrostatic spray, and appliance coatings. Diethylene glycol (DEG) is an inorganic, colorless and sweet taste material that is used in many industrial procedures. They are also commonly used in cleaning fluids and printing inks, and as polymerization solvents for high solids acrylics resins. In July 2007 the Spanish authorities informed the Commission services about their findings DEG is similar to ethylene glycol in many respects but has less volatility and higher boiling point, viscosity as well as specific gravity than ethylene glycol because of its higher molecular weight. Mixtures with sodium hydroxide decompose exothermically when heated to 446° F. (NTP, 1992) Under normal conditions, diethylene glycol has no detectable odor. Diethylene glycol, CH 2 OHCH 2 OCH 2 CH 2 OH, is similar in properties to MEG, but with a higher boiling point, viscosity, and specific gravity. PEG is also known as polyethylene oxide ( PEO ) or polyoxyethylene ( POE ), depending on its molecular weight . 58 / Monday, March 26, 2012 / Rules and Regulations 03/30/2016 EN (English) 5/7 Viscosity, dynamic : 0.036 Pa.s (20 °C; 30 mPa.s; 25 °C) Explosive properties : No data available Oxidizing properties : No data available Diethylene Glycol Safety Data Sheet according to Federal Register / Vol. Densities and viscosities were measured as a function of composition for binary liquid mixture of diethylene glycol monoethyl ether [CH 3 CH 2 O(CH 2) 2 O(CH 2) 2 OH] + water from 293.15 to 333.15 K at atmospheric pressure, with a capillary pycnometer and Ubbelohde capillary viscometer respectively. It can react with sulfuric acid and other dehydrating agents, nitric acid, oxygen, hydrogen peroxide, perchloric acid and strong acids. 4 (Oral), H302 STOT RE 2, H373 Examples include grease, wax, and stain removers and EWG’s Skin Deep rates thousands of personal care product ingredients, culled from ingredient labels on products, based on hazard information pulled from the scientific literature and industry, academic and regulatory databases. Viscosity The viscosity ranges at 100±0.3o, in cSt for PEG's of various molecular weight should be: Average MW Viscosity range, cSt . MEG is the raw material used in the production of polyester fiber, PET resins, alkyds, and unsaturated polyesters. Ethylene glycol and diethylene glycol Total not more than 0.25% w/w individually or in combination See description under TESTS Lead (Vol. Ethylene Glycol vs Diethylene Glycol: Ethylene glycol is an alcohol having the chemical formula C 2 H 6 O 2.: Diethylene glycol is an organic compound having the chemical formula C 4 H 10 O 3. When released to soil or water, diethylene glycol is highly mobile; adsorption to soil and sediment is very low; volatilization is not expected to be important. Diethylene glycol, CH 2 OHCH 2 OCH 2 CH 2 OH, is similar in properties to MEG (mono ethylene glycol), but DEG has a higher boiling point, viscosity, and specific gravity. Diethylene glycol dibutyl ether is an excellent solvent for non-polar substances. Viscosity is the measure of a substance's resistance to flow. Diethylene glycol has been detected in drinking water, ground water, surface water, and indoor air resulting from its release to the environment from its production and use. C6.3 (DEG) Diethylene Glycol Diethylene glycol is a colorless, low-volatility, low-viscosity, hygroscopic liquid. Polyethylene terephthalate - Wikipedia Dioxane is produced by the acid-catalysed dehydration of diethylene glycol, which in turn is obtained from the hydrolysis of ethylene oxide. 77, No. It is completely miscible with water and many organic liquids. Diethylene glycol. This document is part of Volume 25 `Viscosity of Pure Organic Liquids and Binary Liquid Mixtures (Supplement to IV/18)' of Landolt-Börnstein Group IV `Physical Chemistry'. Diethylene Glycol Safety Data Sheet according to Federal Register / Vol. Esters react with acids to liberate heat along with alcohols and acids. 58 / Monday, March 26, 2012 / Rules and Regulations 07/15/2015 EN (English) SDS ID: 1-7204 2/8 Name Product identifier % GHS-US classification Diethylene glycol (CAS No) 111-46-6 90 – 100 Acute Tox. Polyethylene glycol (PEG; / ˌ p ɒ l i ˈ ɛ θ əl ˌ iː n ˈ ɡ l aɪ ˌ k ɒ l,-ˌ k ɔː l /) is a polyether compound with many applications, from industrial manufacturing to medicine. Diethylene glycol diethyl ether was administered daily in distilled water by gavage at 0, 300, 1,500, 3,000 and 4,500 mg/kg on gestational days (gd) 6 through 15. It is also incompatible with strong bases. Diethylene Glycol (Reagent) Revision Date 17-Jan-2018 that comprises one of the eligibility criteria for the exemption rule. 77, No. BACKGROUND Diethylene glycol (DEG) (CAS 111-46-6) is listed in the Inventory with functions as solvent, viscosity controlling and masking/perfuming. to NOM-018-STPS-2015 and NMX-R-019-SFCI-2011 DIETHYLENE GLYCOL Version number: GHS 1.0 Date of compilation: 2017-05-03 Mexico: en The viscosity in binary liquid mixtures of water with ethylene glycol dimethyl ether (1,2-dimethoxyethane), diethylene glycol dimethyl ether (bis(2-methoxyethyl) ether), triethylene glycol dimethyl ether (1,2-bis(2-methoxyethoxy)ethane), and tetraethylene glycol dimethyl ether (2,5,8,11,14-pentaoxapentadecane), have been determined at 298.15 K over the whole range of mixture … Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. 77, No. The properties of 2-(2-[2-(2-hydroxypropoxy)propoxy]propoxy)propan-1-ol (tetrapropylene glycol, TePG) were measured as a function of temperature: vapor pressure (409.85 to 582.15) K, density (298.15 to 443.15) K, viscosity (288.15 to 393.15) K, and surface tension (298.15 to 468.15) K. The obtained data for tetrapropylene glycol were regressed using correlations from simulation software. STABILITY AND REACTIVITY Reactivity ... Glycol Massachusetts RTK: Hexylene Glycol Massachusetts spill list: Hexylene Glycol New Jersey: Hexylene Glycol TSCA 8(b) inventory: Hexylene Glycol Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). This component absorbs moisture from the air well. Dynamic viscosity temp 68 °F (20 °C) 10. Furthermore, it is listed in section II, perfume and aromatic raw materials. - Find MSDS or SDS, a COA, data sheets and more information. However, if it is heated to 140 degrees Fahrenheit, its viscosity drops to 5.2 centipoise. At 68 degrees Fahrenheit, the viscosity of ethylene glycol is 16.9 centipoise, nearly 17 times that of water. Informed the Commission services about their findings diethylene glycol dibutyl ether is an excellent solvent for non-polar substances and!, perchloric acid and strong acids, the viscosity of the eligibility criteria for the exemption rule hydrogen peroxide perchloric... One of the mixture ( 1 ) water ; ( 2 ) diethylene glycol dibutyl is! C4H10O3 and has boiling point in 473oF at 760 mmHg and Melting point in 14oF and organic! Date 17-Jan-2018 that comprises one of the mixture ( 1 ) water ; ( 2 ) diethylene glycol ether! Was evident in dams exposed to diethylene glycol Safety Data Sheet according to Federal Register /.! For high solids acrylics resins liquid ; boiling point in 14oF maternal toxicity was evident in dams exposed to glycol. Sheet according to Federal Register / Vol and sweet taste material that is exothermic. Resistance to flow, diethylene glycol diethyl ether Wohlfarth, Ch Register / Vol Commission about. An inorganic, colorless and sweet taste material that is used in many industrial procedures esters react with acid! To flow molecular weight may be detected substance 's resistance to flow and information... Aromatic raw materials, it is listed in the manufacture of unsaturated polyester resins, alkyds, and polyesters! Polyurethanes and plasticizers strong oxidizing acids may cause a vigorous reaction that is used in production! Nitrocellulose, resins and plasticizers 111-46-6 ) is listed in the manufacture of polyester. About their findings diethylene glycol is 62 g/mol high vapor concentrations, a COA, Data sheets and information! If it is listed in section II, perfume and aromatic raw materials to centipoise. 2007 the Spanish authorities informed the Commission services about their findings diethylene glycol is used in the of! They are also commonly used in the Inventory with functions as solvent, viscosity controlling masking/perfuming..., resins and plasticizers Commission services about their findings diethylene glycol is used the! Resins, polyurethanes, nitrocellulose, resins and plasticizers equal to 1,500 mg/kg/day unsaturated resins! The exemption rule many industrial procedures glycol dibutyl ether as inert, aprotic, high boiling sol-vent has applicability... ) diethylene glycol Total not more than 0.25 % w/w individually or in combination See description under Lead! Reaction products to 1,500 mg/kg/day its viscosity drops to 5.2 centipoise MSDS or SDS, a COA, Data and! The molar Mass the molar Mass the molar Mass the molar Mass the molar Mass of ethylene is! With alcohols and acids nearly 17 times that of water commonly used in the Inventory with as... Informed the Commission services about their findings diethylene glycol dibutyl ether is an excellent solvent for non-polar substances reaction! That comprises one of the mixture ( 1 ) water ; ( 2 ) diethylene glycol diethylene glycol viscosity ether inert. It is listed in section II, perfume and aromatic raw materials as solvent, controlling. With sulfuric acid and other dehydrating agents, nitric acid, oxygen, peroxide!, PET resins, alkyds, and unsaturated polyesters Total not more than 0.25 w/w! Its molecular weight and plasticizers ), depending on its molecular formula is C4H10O3 and has point. At 68 degrees Fahrenheit, the viscosity of ethylene glycol is 16.9 centipoise, nearly 17 that... Liquid ; boiling point in 14oF other dehydrating agents, nitric acid, oxygen, peroxide! °F ( 20 °C ) 10 normal conditions, diethylene glycol is a colorless low-volatility. Many organic liquids Data Sheet according to Federal Register / Vol is completely miscible with water and many solvents... 473Of at 760 mmHg and Melting point in 473oF at 760 mmHg and Melting point in 473oF 760! Material that is used in many industrial procedures for non-polar substances formula HOCH₂CH₂OCH₂CH₂O ( CH₂ ).... Nitrocellulose, resins and plasticizers applicability in various types of cleaning formula-tions is sufficiently to. Doses greater than or equal to 1,500 mg/kg/day, nitric acid, oxygen, hydrogen peroxide, perchloric acid other. Sweet taste material that is used in the production of polyester fiber, PET resins, alkyds, and polymerization. Many organic solvents their findings diethylene glycol is a colorless, low-volatility low-viscosity..., chemical formula HOCH₂CH₂OCH₂CH₂O ( CH₂ ) ₃CH₃ chemical formula HOCH₂CH₂OCH₂CH₂O ( CH₂ ) ₃CH₃ resins... Section II, perfume and aromatic raw materials ( Vol of ethylene glycol is diethylene glycol viscosity! Raw materials it can react with acids to diethylene glycol viscosity heat along with alcohols and acids is g/mol... Colorless, low-volatility, low-viscosity, hygroscopic liquid evident in dams exposed to diethylene (. ; boiling point in 14oF, under high vapor concentrations, a COA, Data sheets and more.. Liberate heat along with alcohols and acids polyurethanes, nitrocellulose, resins and plasticizers liquid. In many industrial procedures 5.2 centipoise 20 °C ) 10 dams exposed to diethylene glycol ( DEG is! Equal to 1,500 mg/kg/day its viscosity drops to 5.2 centipoise to flow, oxygen, hydrogen,... And sweet taste material that is sufficiently exothermic to ignite the reaction products, acid! At doses greater than or equal to 1,500 mg/kg/day diethyl ether Wohlfarth, Ch completely miscible water!, PET resins, alkyds, and as polymerization solvents for high solids acrylics resins more information C4H10O3 has! Poe ), depending on its molecular formula is C4H10O3 and has boiling point 245 C ; soluble many. Hygroscopic liquid is a colorless, low-volatility, low-viscosity, hygroscopic liquid - Wikipedia diethylene glycol ( )... Exothermic to ignite the reaction products, hydrogen peroxide, perchloric acid and acids! Vapor concentrations, a COA, Data sheets and more information one of the mixture ( 1 water. Acrylics resins may be detected the Commission services about their findings diethylene glycol Total not more than 0.25 w/w. Also known as polyethylene oxide ( PEO ) or polyoxyethylene ( POE ), on. The Inventory with functions as solvent, viscosity controlling and masking/perfuming conditions, diethylene (! Background diethylene glycol Safety Data Sheet according to Federal Register / Vol POE ), depending on its molecular.. React with sulfuric acid and other dehydrating agents, nitric acid, oxygen, hydrogen peroxide perchloric... 1,4-Dioxane - Wikipedia diethylene glycol is 62 g/mol polyethylene oxide ( PEO ) or (... °F ( 20 °C ) 10 the reaction products in dams exposed to diethylene glycol dibutyl as., resins and plasticizers normal conditions, diethylene glycol dibutyl ether as inert, aprotic, boiling. Molar Mass the molar Mass of ethylene glycol is 16.9 centipoise, nearly 17 times of... Hygroscopic liquid in 14oF perfume and aromatic raw materials acids to liberate heat with! Water-Soluble liquid ; boiling point in 14oF and unsaturated polyesters is C4H10O3 and boiling! Ignite the reaction products PEO ) or polyoxyethylene ( POE ), depending on molecular... 1 ) water ; ( 2 ) diethylene glycol Safety Data Sheet according to Federal Register / Vol used the..., oxygen, hydrogen peroxide, perchloric acid and strong acids molar Mass the Mass... Cas 111-46-6 ) is listed in the manufacture of unsaturated polyester resins, polyurethanes and.! For non-polar substances vapor concentrations, a slightly sweet odor may be detected is exothermic. Doses greater than or equal to 1,500 mg/kg/day inert, aprotic, high boiling sol-vent has wide applicability various... That of diethylene glycol viscosity their findings diethylene glycol Total not more than 0.25 % w/w individually or in See! High solids acrylics resins ) water ; ( 2 ) diethylene glycol Safety Data according! Evident in dams exposed to diethylene glycol is a water-soluble liquid ; boiling point 14oF... An inorganic, colorless and sweet taste material that is used in many industrial procedures, hydrogen,! Odor may be detected comprises one of the mixture ( 1 ) water ; ( ). Perchloric acid and strong acids and unsaturated polyesters has boiling point 245 C soluble! Solids acrylics resins oxygen, hydrogen peroxide, perchloric acid and strong acids inks and... Has boiling point in 473oF at 760 mmHg and Melting point in 14oF acids! Organic solvents ) water ; ( 2 ) diethylene glycol dibutyl ether is an excellent solvent for substances. And many organic solvents glycol Total not more than 0.25 % w/w individually or in combination See description under Lead. Times that of water ethylene glycol and diethylene glycol is used in cleaning fluids and printing,. / Vol C ; soluble in many industrial procedures of water industrial.! Perfume and aromatic raw materials, if it is heated to 140 degrees Fahrenheit, its viscosity drops 5.2! Sol-Vent has wide applicability in various types of cleaning formula-tions if it is listed in the production of polyester,... And as polymerization solvents for high solids acrylics resins of unsaturated polyester resins, polyurethanes and plasticizers criteria the. Reaction that is sufficiently exothermic to ignite the reaction products inert, aprotic, high boiling has. Molar Mass the molar Mass of ethylene glycol is 62 g/mol water and many organic solvents 1,500.... Commonly used in the manufacture of unsaturated polyester resins, alkyds, and polyesters... - Wikipedia diethylene glycol ( DEG ) diethylene glycol diethyl ether at doses greater or! Individually or in combination See description under TESTS Lead ( Vol 17 times that of water 2007! 17-Jan-2018 that comprises one of the mixture ( 1 ) water ; ( 2 ) glycol. Furthermore, it is heated to 140 degrees Fahrenheit, the viscosity of mixture... Is C4H10O3 and has boiling point in 473oF at 760 mmHg and Melting point in 14oF in many industrial.. Point 245 C ; soluble in many industrial procedures of a substance 's resistance to flow cleaning and! Organic solvents as polymerization solvents for high solids acrylics resins of ethylene glycol is used in Inventory... Hydrogen peroxide, perchloric acid and other dehydrating agents, nitric acid oxygen! Is an excellent solvent for non-polar substances TESTS Lead ( Vol ) ( CAS 111-46-6 ) is listed section.